Go to campaign lobby, and press X to bring up Campaign Options (this also allows you you to turn on Campaign Scoring which is only fun with Friends) and below the choices for the Campaign Scoring are the Skulls. You can only activate ones you have collected in the game, and if playing with friends you don't have to touch them yourself, one of your buddies has to. You just press A and the skull should light up, then back out and play whatever Campaign Mission you desire. I have all the skulls and if you would like help look for me online, gamer tag same as name here.